Publications

2024

125. SEDENHO, G. C.; NASCIMENTO, S. Q.; ZAMANI, M.; CRESPILHO, F. N.; FURST, A. Secondary Structure in Enzyme-Inspired Polymer Catalysts Impacts Water Oxidation Efficiency. Advanced Science, 2402234, 2024. [full text]

124. NASCIMENTO, S. Q.; IOST, R. M.; OLIVEIRA, T. C.; COLOMBO, R. N.; FARIA, L. C. I.; BERTAGLIA, T.; PACHECO, J. C.; OLIVEIRA, M. N.; MANULI, E. R.; PEREIRA, G. M.; SABINO, E. C.; CRESPILHO, F. N. Low-cost ultrasensitive flexible carbon fiber-based biosensor for the detection of SARS-CoV-2 in human saliva. Biosensors and Bioelectronics: X, 100472, 2024. [full text]

123. FARIA, L. C. I.; SEDENHO, G. C.; BERTAGLIA, T.; MACEDO, L. J. A.; CRESPILHO, F.N. A Comparative Study of Chemically Oxidized Carbon Cloth and Thermally Treated Carbon Paper Electrodes applied on Aqueous Organic Redox Flow Batteries. Electrochimica Acta, 144086, 2024. [full text]

122. IOST, R. M.; RADHAKRISHNAN, V.; NASCIMENTO, S. Q.; LIMA, F. H. B.; CRESPILHO, F.N. Hydrogen Bioelectrogeneration with pH-Resilient Oxygen-Tolerant Cobalt Apoenzyme-Saccharide. Chemical Communications, 60, p.2509-2511, 2024. [full text]

2023

121. HASSAN, A.; COLOMBO, R. N. P.; IOST, R. M.; CRESPILHO, F. N. Amplifying Sensing Performance through Gold Micropatterns-induced Modulation of Graphene's Vertical Electron Transfer. Electrochimica Acta, 143069, 2023.[full text]

120. MATTIOLI, I. A.; CASTRO, K. R.; SEDENHO, G. C.; MACEDO, L. J. A.; OLIVEIRA, M. N.; MANULIE, E. R.; SABINO, E. C.; CRESPILHO, F. N. Expanding the application to dual femtomolar detection of SARS-CoV-2 receptor binding domain in serum and saliva. Biosensors and Bioelectronics, 115614, 2023.[full text]

119. MENDES, G. R.; MODENEZ, I. A.; CAGNANI, G. R.; COLOMBO, R. N. P.; CRESPILHO, F. N. Exploring Enzymatic Conformational Dynamics at Surfaces through µ-FTµIR Spectromicroscopy. Analytical Chemistry, 2023.[full text]

118. SEDENHO, G. C.; COLOMBO, R. N. P.; CRESPILHO, F. N. Insights from Enzymatic Catalysis: A Path towards Bioinspired High-Performance Electrocatalysts. ChemCatChem, n.15, v.15, e202300491, 2023.[full text]

117. HASSAN, A.; MATTIOLI, I. A.; COLOMBO, R. N. P.; CRESPILHO, F. N. Tunning quantum capacitance in 2D graphene electrodes: the role of defects and charge carriers concentration. Journal of Materials Chemistry C, n.19, v.11, p.6301-6305, 2023.[full text]

116. CASTRO, K. P. R., COLOMBO, R. N. P., IOST, R. M., SILVA, B. G. R.; CRESPILHO, F. N. Low-dimensionality carbon-based biosensors: the new era of emerging technologies in bioanalytical chemistry. Analytical and Bioanalytical Chemistry, v.415, p.3879-3895, 2023.[full text]

2022

115. CAGNANI, G. R.; OLIVEIRA, T. C.; MATTIOLI, I. A.; SEDENHO, G. S.; CASTRO, K. P. R.; CRESPILHO, F. N. From research to market: correlation between publications, patent filings, and investments in development and production of technological innovations in biosensors. Analytical and Bioanalytical Chemistry, v.415, p.3645-3653, 2022. [full text]

114. COLOMBO, R. N. P; SEDENHO, G. C.; CRESPILHO, F.N. Challenges in Biomaterials Science for Electrochemical Biosensing and Bioenergy. Chemistry of Materials, v.34, n.23, p.10211-10222, 2022. [full text]

113. SEDENHO, G.C.; NECKEL, I. T.; COLOMBO, R. N. P.; PACHECO, J. C.; BERTAGLIA, T.; CRESPILHO, F.N. Investigation of Water Splitting Reaction by a Multicopper Oxidase through X-ray Absorption Nanospectroelectrochemistry. Advanced Energy Materials, v.12, n.47, 2202485, 2022. [full text]

112. ALI, M. A.; SEDENHO, G. C.; PACHECO, J. C.; IOST, R. M..; RAHMAN, A.; HASSAN, A.; CARDOSO, D. R.; GOMES, R. S.; CRESPILHO, F. N. Metal-free, low cost, and high performance membraneless ethanol fuel cell. Journal of Power Sources, v.551, 232164, 2022. [full text]

111. SEDENHO, G.C.; HASSAN, A.; SOUZA, J. C. P.; CRESPILHO, F. N. In Situ Operando Electrochemistry of Redox Enzymes. Current Opinion in Electrochemistry, v.34, 101015, 2022. [full text]

110. MACEDO, L. J. A.; RODRIGUES, F. P.; HASSAN, A.; MÁXIMO, L. N. C.; ZOBI, F.; SILVA, R. S.; CRESPILHO, F.N. Non-destructive molecular FTIR spectromicroscopy for real time assessment of redox metallodrugs. Analytical Methods, v.14, n.11, p.1094-1102, 2022. [full text]

109. MATTIOLI, I. A.; CASTRO, K. R.; MACEDO, L. J. A.; SEDENHO, G. C.; OLIVEIRA, M. N.; TODESCHINI, I.; VITALE, P. M.; FERREIRA, S. C.; MANULI, E. R.; PEREIRA, G. M.; SABINO, E. C.; CRESPILHO, F. N. Graphene-based hybrid electrical-electrochemical point-of-care device for serologic COVID-19 diagnosis. Biosensors and Bioelectronics, v.199, 113866, 2022. [full text]

2021

108. SANCHES, N. M.; HASSAN, A.; MATTIOLI, I. A.; MACEDO, L. J. A.; SEDENHO, G. C.; CRESPILHO, F. N. Tuning Vertical Electron Transfer on Graphene Bilayer Electrochemical Devices. Advanced Materials Interfaces,, v.8, n.20, 2100550, 2021. [full text]

107. HASSAN, A.; SEDENHO, G. C.; VITALE, P. A. M.; OLIVEIRA, M. N.; CRESPILHO, F. N. On the weak binding and spectroscopic signature of SARS-CoV-2 nsp12 interaction with RNA. ChemBioChem, v.22, n.24, p.3410-3413, 2021 [full text]

106. SEDENHO, G.C.; MODENEZ, I.; MENDES, G. R.; CRESPILHO, F. N. The role of extracellular polymeric substance matrix on Saccharomyces cerevisiae bioelectricity. Electrochimica Acta, v.393, n.10, 139080, 2021. [full text]

105. MACEDO, L. J. A.; SANTO, A. A. E.; SEDENHO, G. C.; HASSAN, A.; IOST, R. M.; FELICIANO, G. T.; CRESPILHO, F. N.. Three-Dimensional Catalysis and the Efficient Bioelectrocatalysis Beyond Surface Chemistry. Journal of Catalysis, v. 401, p. 200-205, 2021. [full text]

104. MODENEZ, I. A.; MACEDO, L. J. A.; MELO, A. F. A. A.; PEREIRA, A. R.; OLIVEIRA JR, O. N.; CRESPILHO, F. N. Nanosized non-proteinaceous complexes III and IV mimicking electron transfer of mitochondrial respiratory chain. Journal of Colloid and Interface Science, v. 599, p.198-206, 2021. [full text]

103. HASSAN, A.; MACEDO, L. J. A.; MATTIOLI, I. A.; RUBIRA, R. J.G.; CONSTANTINO, C. J. L.; AMORIM, R. G.; LIMA, F. C. D. A.; CRESPILHO, F. N. A three component-based van der Waals surface vertically designed for biomolecular recognition enhancement. Electrochimica Acta, v. 376, 138025, 2021. [full text]

102. MATTIOLI, I. A.; HASSAN, A.; SANCHES, N. M.; VIEIRA, N. C. S.; CRESPILHO, F. N. Highly sensitive interfaces of Graphene electrical-electrochemical vertical devices fro on drop atto-molar DNA detection. Biosensors and Bioelectronics, v.175, 112851, 2021. [full text]

101. SEDENHO, G. C.; HASSAN, A.; MACEDO, L. J. A.; CRESPILHO, F. N. Stabilization of bilirubin oxidase in a biogel matrix for high-performance gas diffusion electrodes. Journal of Power Sources, v.482, n.15 , 229035, 2021. [full text]

100. SOUZA, J. C. P.; MACEDO, L. J. A.; HASSAN, A.; SEDENHO, G. C.; MODENEZ, I. A.; CRESPILHO, F. N. In Situ and Operando Techniques for Investigating Electron Transfer in Biological Systems. ChemElectroChem, v.8, n.3, p.431-446, 2021. [full text]

2020

99. MATTIOLI, I. A.; HASSAN, A.; OLIVEIRA JUNIOR, O. N.; CRESPILHO, F. N. On the Chanllenges for the Diagnosis of SARS-CoV-2 Based on a Review of Current Methodologies. ACS Sensors, v.5, n.12, p.3655-3677, 2020. [full text]

98. MATTIOLI, I. A.; CRESPILHO, F. N. Problems of Interpreting Diagnostic Tests for SARS-CoV-2: Analytical Chemistry Concerns. Anais da Academia Brasileira de Ciências, v.92, n.4, e20201208, 2020. [full text]

97. HASSAN, A.; MACEDO, L. J. A.; CRESPILHO, F. N. Recognizing Conductive Islands in Polymeric Redox Surface Using Electrochemical-Coupled Vibration Spectromicroscopy. Chemical Communications, v.56, p.10309-10312, 2020. [full text]

96. IMAMURA, A. H.; SEGATO, T. P.; OLIVEIRA, L. J. M.; HASSAN, A.; CRESPILHO, F. N.; CARRILHO, E. Monitoring cellulose oxidation for protein immobilization in paper-based low-cost biosensors. Microchimica Acta, 187, 272, 2020. [full text]

95. OSICA, I.; MELO, A. F. A. A.; LIMA, F. C. D. A.; SHIBA, K.; IMAMURA, G.; CRESPILHO, F. N.; BETLEJ, J.; KURZYDOWSKI, K. J.; YOSHIKAWA, G.; ARIGA, K. Nanomechanical Recognition and Discrimination of Volatile Molecules by Au Nanocages Deposited on Membrane-Type Surface Stress Sensors. ACS Applied Nano Materials, v.3, n.5, p.4061-4068, 2020. [full text]

94. HASSAN, A.; MACEDO, L. J. A.; SOUZA, J. C. P.; LIMA, F. C. D. A.; CRESPILHO, F. N. A combined Far-FTIR, FTIR Spectromicroscopy, and DFT Study of the Effect of DNA Bindind on the [4Fe4S] Cluster Site in EndoIII. Scientific Reports, 10, 1931, 2020. [full text]

93. SEDENHO, G. C.; PORCELLINIS, D.; JING, Y.; KERR, E.; MEIJA-MENDOZA, L. M.; VÁZQUEZ-MAYAGOITIA, A.; ASPURU-GUZIK, A.; GORDON, R. G.; CRESPILHO, F. N.; AZIZ, M. J. Effect of molecular structure of quinones and carbon electrode surfaces on the interfacial electron transfer process. ACS Applied Energy Materials, v.3, n. 2, p.1933-1943, 2020. [full text]

92. MACEDO, L. J. A.; HASSAN, A.; SEDENHO, G. C.; CRESPILHO, F. N. Assessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy. Nature Communications, v.11, n. 316, 2020. [full text]

91. RODRIGUES, F. P.; MACEDO, L. J. A.; MÁXIMO, L. N. C.; SALES, F. C. P. F.; DA SILVA, R. S.; CRESPILHO, F. N. Real-time redox monitoring of a nitrosyl ruthenium complex acting as NO-donor agent in a single A549 cancer cell with multiplex Fourier-transform infrared microscopy. Nitric Oxide, v.96, n.1, p. 29-34, 2020. [full text]

2019

90.IOST, R.M.; MARTINS, M. V. A.; CRESPILHO, F. N. Dendritic Gold Nanoparticles Towards Transparent and Electroactive Electrodes. Anais da Academia Brasileira de Ciências. v. 91, n. 4, p. 1-13, 2019. [full text]

89. CRESPILHO, F.N.; SEDENHO, G. C.; PORCELLINIS, D. D.; KERR, E.; GRANADOS-FOCIL, S.; GORDON, R.G.; AZIZ, M.J. Non-corrosive, Low-Toxicity Gel-based Microbattery from Organic and Organometallic Molecules. Journal of Materials Chemistry A, v.7, p.24784- 24787, 2019. [full text]

88. MELO, A. F. A. A.; SEDENHO, G.; OSICA, I.; ARIGA, K.; CRESPILHO, F. N. Electrochemical behaviour of cytochrome c immobilized in magnetically induced mesoporous framework. ChemElectroChem, 2019. [full text]

87. KHALID, M.; HASSAN, A.; HONORATO, A. M. B.; CRESPILHO, F. N.; VARELA, H. 8-Hydroxyquinoline-5-sulfonic on reduced graphene oxide layers as a metal-free elctrode material for supercapacitor applications. Journal of Electroanalytical Chemistry, v. 847, p. 113193-113199, 2019. [full text]

86. ALI, M. A.; HASSAN, A.; SEDENHO, G. C.; GONÇALVES, R. V.; CARDOSO, D. R.; CRESPILHO, F. N. Operando Electron Paramagnetic Resonance for Elucidating the Electron Transfer Mechanism of Coenzymes. The Journal of Physical Chemistry C, v. 123, p. 16058-16064 2019. [full text]

85. MELO, A. F. A. A.; OSICA, I.; SHRESTHA, L. K.; JI, Q.; MACEDO, L. J. A.; HASSAN, A.; OLIVEIRA, O. N.; HENZIE, J.; ARIGA, K.; CRESPILHO, F. N. Microwaves of Au-Ag nanocages patterned via magnetic nanoadhesives for investigating proteins usin surface enhanced infrared absorption spectroscopy. ACS Applied Materials and Interfaces, v.11, n. 20, p.18053-18061, 2019. [full text]

84. MACEDO, L. J. A.; IOST, R. M.; HASSAN, A.; BALASUBRAMANIAN , K.; CRESPILHO, F. N. Bioelectronics and Interfaces Using Monolayer Graphene. ChemEletroChem, v. 6, p. 31-39, 2019. [full text]

83. BARRETO, C. G. R.; KAWAI, A.; TOFANELLO, A.A.R.; NEVES, J.C.; ARAUJO-CHAVES, E.; BELLETI, E.; LANFREDI, A. J. C.; CRESPILHO, F. N.; NANTES-CARDOSO, I.L. Magnetolipossomes as model for signal transmission. Royal society open science, v.6, 2019. [full text]

82. MARTIN, C. S.; ALESSIO, P.; CRESPILHO, F. N.; BRETT, C. M. A.; CONSTANTINO, C. J. L. Influence of supramolecular arrangement of iron phthalocyanine thin films on catecholamine oxidation. Journal of Electroanalytical Chemistry, v. 836, 7-15, 2019. [full text]

81.BECHER, T. B.; BRAGA, C.B.; BERTUZZI, D.L.; RAMOS JR, M. D.; HASSAN, A.; CRESPILHO, F. N.; ORNELAS, C. The structure- property relationship in LAPONITE® materials: from Wigner glasses to strong self-healing hydrogels formed by non-covalent interactions. Soft Matter, v.15, 1278-1289, 2019. [full text]

2018

80. KHALID, M., HASSAN, A.,HONORATO, A. M., CRESPILHO, F. N., VARELA, H. Nano-flocks of a bimetallic organic frammework for efficient hydrogen evolution electrocatalysis. Chem. Commun, v. 54, 11048-11051, 2018 . [full text]

79. MACEDO, L. J. A., LIMA, F. C. D. A., AMORIM, R. G., FREITAS, R. O., YADAV, A., IOST, R. M., K. BALASUBRAMANIAN, CRESPILHO, F. N. Interplay of non-uniform charge distribution on the electrochemical modification of graphene. Nanoscale, v.10, 15048-15057, 2018. [full text]

78. MARTIN, C. S., ALESSIO, P., CRESPILHO, F. N., CONSTANTINO, C. J. Supramolecular Arrangement of Iron Phthalocyanine in Langmuir-Schaefer and Electrodeposited Thin Films. Journal of nanoscience and nanotechnology, v. 18, 3206-3217, 2018. [full text]

77.PEREIRA, A. R., SEDENHO, G. C., SOUZA, J. C. P., & CRESPILHO, F. N.. Advances in enzyme bioelectrochemistry. Anais da Academia Brasileira de Ciencias, v. 90, 825-857, 2018. [full text]

76. CRESPILHO, F. N. Commemorative Volume on the Centenary of the Brazilian Academy of Sciences:“Brazil: Frontiers of Chemical Sciences”. Anais da Academia Brasileira de Ciências, v. 90, 591-592, 2018. [full text]

75. PAGNONCELLI, K.C.; PEREIRA, A. R.; SEDENHO, G. C.; BERTAGLIA,T.; CRESPILHO, F. N. Ethanol generation, oxidation and energy production in a cooperative bioelectrochemical system. Bioelectrochemistry, v. 122, 11-25, 2018. [full text]

74. MACEDO, L. J. A.; CRESPILHO, F. N. Multiplex Infrared Spectroscopy Imaging for Monitoring Spatially Resolved Redox Chemistry. Analytical Chemistry, v. 90, 1487-1491, 2018. [full text]

2017

73. OSICA, I; MELO, A. F. A.; IMAMURA, K. S. ; JI, Q.; HILL, J.P.; .; CRESPILHO, F. N.;KURZYDŁOWSKI, K. J.; YOSHIKAWA, G.; ARIGA, K. Fabrication of Silica-Protein Hierarchical Nanoarchitecture with Gas-Phase Sensing Activity. Journal of Nanoscience and Nanotechnology, 17 (8), 5908-5917, 2017.[full text]

72. SOUZA, J. C. P.; SILVA, W.; LIMA, F. H. B.; CRESPILHO, F. N. Enzyme Activity Evaluation by Differential Electrochemical Mass Spectrometry. Chemical Communications, v.53, 8400-8402, 2017.[full text]

71. PEREIRA, A. R.; SOUZA, J. C. P.;GONÇALVES, A. D.;PAGNONCELLI, K. C.; CRESPILHO, F. N. Bioelectrooxidation of Ethanol Using NAD-Dependent Alcohol Dehydrogenase on Oxidized Flexible Carbon Fiber Arrays . Journal of the Brazilian Chemical Society, v.28, 1698-17-07, 2017.[full text]

70. PEREIRA, A. R.; LUZ, R. A. S.; LIMA, F. C. D. A.; CRESPILHO, F. N. Protein Oligomerization Based on Brønsted Acid Reaction . ACS Catalysis, 2017, v.7, 3082-3088. [full text]

69. BARTELS, P. L.; ZHOU, A.; ARNOLD, A. R.; NUÑEZ, N. N.; CRESPILHO, F. N.; DAVID, S. S.; BARTON, J. K. Electrochemistry of the [4Fe4S] Cluster in Base Excision Repair Proteins: Tuning the Redox Potential with DNA. Langmuir, 2017, v.33, 2523-2530. [full text]

2016

68. IOST, R. M.; CRESPILHO, F N.; KERN, K.; BALASUBRAMANIAN, K. A primary battery-on-a-chip using monolayer graphene. Nanotechnology, 2016. [full text]

67. LUZ, R. A. S.; CRESPILHO, F N. Gold Nanoparticle-mediated Electron Transfer of Cytochrome c on a Self-Assembled Surface. RSC Advances, v. 6, 62585-62593, 2016. [full text]

66. MARTIN, C. S.; GOUVEIA-CARIDADE, C.; CRESPILHO, F. N.; CONSTANTINO, C. J. L.; BRETT, C. M.A. Iron Phthalocyanine Electrodeposited Films: Characterization and Influence on Dopamine Oxidation. Journal of Physical Chemistry. C, v.120, n. 29, p.15698-15706, 2016 [full text]

65. PEREIRA, A. R.; SOUZA, J. C. P.; IOST, R. M.; SALES, F. C. P. F.; CRESPILHO, F. N. Application of carbon fibers to flexible enzyme electrodes. Journal of Electroanalytical Chemistry, v.780, p.396-406, 2016. [full text]

64. SOUZA, J. C. P.; IOST R. M.; CRESPILHO, F. N. Nitrated carbon nanoblisters for High-performance glucose dehydrogenase bioanodes. Biosensors and Bioelectronics, v. 77, 860–865, 2016. [full text]

63. CABRERA, F. C.; DOGNANI, G.; FAITA, F. L.; DOS SANTOS, R. J.; AGOSTINI, D. L. S.; BECHTOLD, I. H.; CRESPILHO, F. N.; JOB, A. E. Vulcanization, centrifugation, water-washing, and polymeric covering processes to optimize natural rubber membranes applied to microfluidic devices. Journal of Materials Science, 2016, v. 51, 3003-3012. [full text]

2015

62. MARTIN, C. S.; GOUVEIA-CARIDADE, C.; CRESPILHO, F. N.; CONSTANTINO, C. J.; BRETT, C. M. Nickel-N, N’–bis (salicylidene)-1, 3-propanediamine (Ni-Salpn) film-modified electrodes. Influence of electrodeposition conditions and of electrode material on electrochemical behaviour in aqueous solution. Electrochimica Acta, 2015, v. 178, 80-91. [full text]

61. CABRERA, F. C. ; MELO, ANTONIO F. A. A.; SOUZA, J. C. P.; JOB, A. E.; CRESPILHO, F. N. A flexible lab-on-a-chip for the synthesis and magnetic separation of magnetite decorated with gold nanoparticles. Lab on a Chip, 2015, v. 15, 1835-1841. [full text]

60. IOST, R.M. ; FERREIRA, F.C.P. ; MARTINS, M.V.A. ; ALMEIDA, M.C. ; CRESPILHO, F.N. Glucose Biochip based on Flexible Carbon Fiber Electrodes: In Vivo Diabetes Evaluation in Rats. ChemElectroChem, 2015, v. 2, 518–521. [full text]

2014

59. LIMA, F. C. D. A.; CALZOLARI, A.; CALDAS, M. J.; IOST, R. M.; CRESPILHO, F. N.; PETRILLI, H. Electronic structure of self-assembled monolayers modified with ferrocene on a gold surface: evidence of electron tunnelling. The Journal of Physical Chemistry C, v. 118, p. 23111-23116, 2014.[full text]

58. IOST, R. M.; CRESPILHO, F. N.; ZUCCARO, L.; YU, H. K.; WODTKE, A. M.; KERN, K.; BALASUBRAMANIAN, K. Enhancing the electrochemical and electronic performance of CVD-grown graphene by minimizing trace metal impurities. ChemElectroChem, v. 1, p. 2070–2074, 2014.[full text]

57. CABRERA, F. C.; SOUZA, J. C. P.; JOB, A. E.; CRESPILHO, F. N. Natural-rubber-based flexible microfluidic device. RSC Advances,v. 4, p. 35467–35475, 2014. [full text]

56. OLIVEIRA, O. N.; IOST R. M.; JUNIOR, J. R. S.; CRESPILHO, F. N.; CASELI, L. Nanomaterial for diagnosis: challenges and aplication in smart devices based on molecular recognition. ACS Applied Materials & Interfaces, v. 6, p. 14745–14766 2014. [full text]

55. LUZ, R. A. S.; PEREIRA, A. R.; SOUZA, J. C.P.; SALES, F. C. P. F.; CRESPILHO, F. N. Enzyme biofuel cells: thermodynamics, kinetics, and challenges in applicability. ChemElectroChem, v. 1, 1751–1777, 2014. [full text]

54. GONÇALVES, W. D.; IOST, R. M.; CRESPILHO, F.N. Diffusion mechanisms in nanoelectrodes: evaluating the edge effect. Electrochimica Acta, v. 123, p. 66-71, 2014. [full text]

53. SANTOS, G. P. ; MELO, A. F. A. A.; CRESPILHO, F. N. Magnetically controlled single-nanoparticle detection via particle-electrode collisions. PCCP. Physical Chemistry Chemical Physics,v. 16 p. 8012-8018, 2014. [full text]

52. MARTINS, M. V. A.; PEREIRA, A. R.; LUZ, R. A. S.; IOST, R. M.; CRESPILHO, F. N. Evidence of short-range electron transfer of a redox enzyme on graphene oxide electrodes. PCCP. Physical Chemistry Chemical Physics, 2014. [full text]

2013

51. ARAÚJO-CHAVES, J. C.; KAWAI, C.; MELO, A. F. A. A.; MUGNOL, K. C. U.; NASCIMENTO, O. R.; ARANTES, J. T.; CRESPILHO, F. N.; NANTES, I. L. Interaction and reaction of the antioxidant MnIII [Meso-Tetrakis(4-NMethyI Pyridinium) Porphyrin] with the apoptosis reporter lipid phosphatidylserine. Current Physical Chemistry, v. 3, p. 187-198, 2013.[full text]

50. SALES, F. C. P. F.; IOST, R. M.; MARTINS, M. V. A.; ALMEIDA, M. C.; CRESPILHO, F. N. An intravenous implantable glucose/dioxygen biofuel cell with modified flexible carbon fiber electrodes. Lab on a Chip, v. 13, p. 468, 2013. [full text]

49. MELO, A. F. A. A.; LUZ, R. A. S.; IOST, R. M.; NANTES, I. L.; CRESPILHO, F. N. Highly stable magnetite modified with chitosan, ferrocene and enzyme for application in magneto-switchable bioelectrocatalysis. Journal of the Brazilian Chemical Society, v. 24, p. 285-294, 2013. [full text]

48. LIANG, R. N.; GONCALVES, W. D.; MARTINS, M. V. A.; CRESPILHO, F. N. Filtros Digitais por Transformadas de Fourier Aplicados em Eletroquímica. Química Nova, v. 31, p. 165-170, 2013. [full text]

47. MELO, A. F. A. A.; CARVALHO, V. A. N.; PAGNONCELLI, K. C.; CRESPILHO, F. N. Single microparticle applied in magnetic-switchable electrochemistry. Electrochemistry Communications, v. 30, p. 79-82, 2013.[full text]

46. SILVA, A. T. B; COELHO, A. G.; LOPES, L. C. S.; MARTINS, M. V. A.; CRESPILHO, F. N.; MERKOÇI, A.; DA SILVA, W. C. Nano-Assembled supramolecular films from chitosan-stabilized gold nanoparticles and cobalt(II) phtalocyanine. Journal of the Brazilian Chemical Society, v. 24, p.1237-1245, 2013. [full text]

45. GOTO, T. E.; SAKAI, A.;IOST, R. M.; DA SILVA, W. C.; PÉRES, L. O.; CRESPILHO, F. N.; CASELI, L. Langmuir-Blodgett films based on poly(p-phenylene vinylene) and protein-stabilised palladium nanoparticles: implications in luminescent and conducting properties. Thin Solid Films, v. 540, p. 202-207, 2013. [full text]

2012

44. OLYVEIRA, G. M.; KIM, J.H.; MARTINS, M. V. A.; IOST, R. M.; CHAUDHARI, K. N.; YU, J. S.; CRESPILHO, F. N. Flexible carbon cloth electrode modified by hollow core-mesoporous shell carbon as a novel efficient bio-anode for biofuel cell. Journal of Nanoscience and Nanotechnology, v. 12, p. 356-360, 2012. [full text]

43. MARANGONI, V. S.; MARTINS, M. V. A.; SOUZA, J. A.; OLIVEIRA, O. N.; ZUCOLOTTO, V.; CRESPILHO, F. N. The processing of polyelectrolyte-covered magnetite nanoparticles in the form of nanostructured thin films. Journal of Nanoparticle Research, v. 14, p. 769-778, 2012. [full text]

42. IOST, R. M.; CRESPILHO, F. N. Layer-by-layer self-assembly and electrochemistry: applications in biosensing and bioelectronics. Biosensors & Bioelectronics, v. 31, p. 1-10, 2012. [full text]

41. CARVALHO, V. A. N.; LUZ, R. A. S.; LIMA, B. H.; CRESPILHO, F. N ; LEITE, E. R. ; SOUZA, F. L. Highly oriented hematite nanorods arrays for photoelectrochemical water splitting. Journal of Power Sources, v. 205, p. 525-529, 2012. [full text]

40. DIAS, C. F. B.; ARAÚJO-CHAVES, J. C.; MUGNOL, K. C. U.; TRINDADE, F. J.; ALVES, O. L.; CAIRES, A. C. F.; BROCHSZTAIN, S. ; CRESPILHO, F. N. ; MATOS, J. R.; NASCIMENTO, O. R. ; NANTES, I. L. Photo-induced electron transfer in supramolecular materials of titania nanostructures and cytochrome c. RSC Advances, v. 1, p. 1-10, 2012. [full text]

2011

39. NANTES, I. L.; CRESPILHO, F. N.; CHAVES, J. C. A.; LUZ, R. A. S.; NASCIMENTO, O. R.; PINTO, S. M. S. Effect of the medium, supramolecular organization and association with colloidal systems on the UV-Visible and magnetic circular dichroism spectra of porphyrinoids. Chemical Physics Research Journal, v. 3, p. 1-10, 2011. [full text]

38. GOTO, T. E.; LOPEZ, R. F.; IOST, R. M.; CRESPILHO, F. N.; CASELI, L. Monolayer collapse regulating process of adsorption-desorption of palladium nanoparticles at fatty acid monolayers at the air-water interface. Langmuir, v. 27, p. 2667-2675, 2011. [full text]

37. IOST, R. M.; DA SILVA, W. C.; MADURRO, J. M.; MADURRO, A. G.; FERREIRA, L. F.; CRESPILHO, F. N. Recent advances in nano-based electrochemical biosensors: application in diagnosis and monitoring of diseases. Frontiers in Bioscience, v. 3, p. 663, 2011. [full text]

36. PEREIRA, A. R.; IOST, R. M.; MARTINS, M. V. A.; YOKOMIZO, C. H.; DA SILVA, W. C.; NANTES, I. L.; CRESPILHO, F. N. Molecular interactions and structure of a supramolecular arrangement of glucose oxidase and palladium nanoparticles. PCCP. Physical Chemistry Chemical Physics, v. 13, p. 12155, 2011. [full text]

35. IOST, R. M.; MADURRO, J. M.; BRITO-MADURRO, A. G.; NANTES, I. L.; CASELI, L.; CRESPILHO, F.N. Strategies of nano-manipulation for application in electrochemical biosensors. International Journal of Electrochemical Science, v. 6, p. 2965-2997, 2011. [full text]

34. GONÇALVES, W. D.; LANFREDI, A. J. C.; CRESPILHO, F. N. Development of numerical methods for signal smoothing and noise modeling in single wire-based electrochemical biosensors. Journal of Physical Chemistry C, v. 115, p. 16172-16179, 2011. [full text]

33. LUZ, R. A. S.; MARTINS, M. V. A.; MAGALHÃES, J. L.; SIQUEIRA, J. R.; ZUCOLOTTO, V.; OLIVEIRA, O. N.; CRESPILHO, F. N.; DA SILVA, W. C. Supramolecular architectures in layer-by-layer films of single-walled carbon nanotubes, chitosan and cobalt (II) phthalocyanine. Materials Chemistry and Physics, v. 130, p. 1072-1077, 2011. [full text]

32. MUGNOL, K. C.; MARTINS, M. V. A.; NASCIMENTO, E. C.; NASCIMENTO, O. R.; CRESPILHO, F. N.; ARANTES, J. T.; NANTES, I. L. Interaction of Fe3+meso-tetrakis (2,6-dichloro-3-sulfonatophenyl) porphyrin with cationic bilayers: magnetic switching of the porphyrin and magnetic induction at the interface. Theoretical Chemistry Accounts, v. 130, p. 829-837, 2011. [full text]

31. GALIOTE, N. A.; CAMARGO, M. N. L.; IOST, R. M.; CRESPILHO, F. N.; HUGUENIN F. Effects of self-assembled materials prepared from V2O5 for lithium ion electroinsertion. Langmuir, v. 27, p. 12209-12217, 2011. [full text]

2010

30. SIQUEIRA, J. R.; CASELI, L.; CRESPILHO, F. N.; ZUCOLOTTO, V.; OLIVEIRA, O. N. Immobilization of biomolecules on nanostructured films for biosensing. Biosensors & Bioelectronics. v. 25, p. 1254-1263, 2010. [full text]

29. SANTOS, A. C.; LUZ, R. A. S.; FERREIRA, L. G. F.; SANTOS Jr., J. R.; SILVA ,W. C.; CRESPILHO, F. N. Organização supramolecular da ftalocianina de cobalto(II) e seu efeito na oxidação do aminoácido cisteína. Química Nova, v. 33, p. 539-546, 2010. [full text]

28. MARTINS, M. V. A.; BONFIM, C.; DA SILVA, W. C.; CRESPILHO, F. N. Iron (III) nanocomposites for enzyme-less biomimetic cathode: a promising material for use in biofuel cells. Electrochemistry Communications, v. 12, p. 1509-1512, 2010. [full text]

2009

27. CRESPILHO, F. N.; LIMA, F. C. A.; DA SILVA, A. B. F.; OLIVEIRA, O.; ZUCOLOTTO, V. The origin of the molecular interaction between amino acids and gold nanoparticles: a theoretical and experimental investigation. Chemical Physics Letters, v. 469, p. 186-190, 2009. [full text]

26. CRESPILHO, F. N.; IOST, R. M.; TRAVAIN, S. A.; OLIVEIRA, O. N. ; ZUCOLOTTO, V. Enzyme immobilization on Ag nanoparticles/polyaniline nanocomposites. Biosensors & Bioelectronics, v. 24, p. 3073-3077, 2009. [full text]

25. ALENCAR, W. S.; CRESPILHO, F. N.; MARTINS, M. V. A.; ZUCOLOTTO, V.; OLIVEIRA, O. N.; SILVA, W. C. Synergistic interaction between gold nanoparticles and nickel phthalocyanine in layer-by-layer (LbL) films: evidence of constitutional dynamic chemistry (CDC). PCCP. Physical Chemistry Chemical Physics, v. 11, p. 5086-5091, 2009. [full text]

24. CRESPILHO, F. N.; ESTEVES, M. C.; SUMODJO, P. T. A.; PODLAHA, E. J. ; ZUCOLOTTO, V. Development of highly selective enzymatic devices based on deposition of permselective membranes on aligned nanowires. Journal of Physical Chemistry C., v. 1133, p. 6037-6041, 2009. [full text]

23. CRESPILHO, F. N.; LANFREDI, A. J. C.; LEITE, E. R.; CHIQUITO, A. J. Development of individual semiconductor nanowire for bioelectrochemical device at low overpotential conditions. Electrochemistry Communications, v. 11, p. 1744-1747, 2009. [full text]

2008

22. CASELI, L.; CRESPILHO, F. N.; NOBRE, T. M.; ZANIQUELLI, M. E. D.; ZUCOLOTTO, V.; OLIVEIRA, O. N. Using phospholipid Langmuir and Langmuir-Blodgett films as matrix for urease immobilization. Journal of Colloid and Interface Science, v. 319, p. 100-108, 2008. [full text]

21. CRESPILHO, F. N.; GHICA, M. E.; GOUVEIA-CARIDADE, C.; OLIVEIRA, O. N.; BRETT, C. M. A. Enzyme immobilisation on electroactive nanostructured membranes (ENM): Optimised architectures for biosensing. Talanta (Oxford), v. 76, p. 922-928, 2008. [full text]

2007

20. AIROLDI, F. P. S.; DA SILVA, W. T. L.; CRESPILHO, F. N.; REZENDE, M. O. O. Evaluation of the electrochemical behavior of pentachlorophenol by cyclic voltammetry on carbon paste electrode modified by humic acids. Water Environment Research, v. 79, p. 63-67, 2007. [full text]

19. CRESILHO, F. N.; GHICA, M. E.; ZUCOLOTTO, V.; NART, F. C.; OLIVEIRA, O. N.; BRETT, C. M. A. Electroactive nanostructured membranes (ENM): synthesis and electrochemical properties of redox mediator-modified gold nanoparticles using a dendrimer layer-by-layer approach. Electroanalysis (New York), v. 19, p. 805-812, 2007. [full text]

18. CRESPILHO, F. N.; NART, F. C.; OLIVEIRA, O. N.; BRETT, C. M. A. Oxygen reduction and diffusion in electroactive nanostructured membranes (ENM) using a layer-by-layer dendrimer-gold nanoparticle approach. Electrochimica Acta, v. 52, p. 4649-4653, 2007. [full text]

17. FRAIGE, K.; CRESPILHO, F. N.; REZENDE, M. O. O. Determinação de zinco em solo utilizando colorimetria. Química Nova, v. 30, p. 588-591, 2007. [full text]

16. ALENCAR, W. S.; CRESPILHO, F. N.; SANTOS, M. R. M. C.; ZUCOLOTTO, V.; OLIVEIRA, O. N.; SILVA, W. C. Influence of film architecture on the charge-transfer reactions of metallophthalocyanine layer-by-layer films. Journal of Physical Chemistry, v. 111, p. 12817-12821, 2007. [full text]

15. SIQUEIRA, J. R.; CRESPILHO, F. N.; ZUCOLOTTO, V.; OLIVEIRA, O. N. Bifunctional electroactive nanostructured membranes. Electrochemistry Communications, v. 9, p. 2676-2680, 2007. [full text]

2006

14. CRESPILHO, F. N.; HUGUENIN, F.; ZUCOLOTTO, V.; OLIVI, P.; NART, F. C.; OLIVEIRA, O. N. Dendrimers as nanoreactors to produce platinum nanoparticles embedded in layer-by-layer films for methanol-tolerant cathodes. Electrochemistry Communications, v. 8, p. 348-352, 2006. [full text]

13. CRESPILHO, F. N.; ZUCOLOTTO, V.; BRETT, C. M. A.; OLIVEIRA, O. N.; NART, F. C. Enhanced charge transport and incorporation of redox mediators in layer-by-layer films containing PAMAM encapsulated-gold nanoparticles. Journal of Physical Chemistry B, v. 110, p. 17478-17483, 2006. [full text]

12. CRESPILHO, F. N.; BORGES, T. F. C. C.; ZUCOLOTTO, V.; LEITE, E. R.; NART, F. C; OLIVEIRA, O. N. Synthesis of core-shell Au@polypyrrole nanocomposite using a dendrimer-template approach. Journal of Nanoscience and Nanotechnology, v. 6, p. 2588-2590, 2006. [full text]

11. CRESPILHO, F. N.; ZUCOLOTTO, V.; SIQUEIRA, J. R.; CARVALHO, A. F. J.; NART, F. C.; OLIVEIRA, O. N. Using electrochemical data to obtain energy diagrams for layer-by-layer films from metallic phthalocyanines. International Journal of Electrochemical Science, v. 1, p. 151-159, 2006. [full text]

10. CRESPILHO, F. N.; GHICA, M. E.; FLORESCU, M.; NART, F. C.; OLIVEIRA, O. N.; BRETT, C. M. A. A strategy for enzyme immobilization on layer-by-layer dendrimer-gold nanoparticle electrocatalytic membrane incorporating redox mediator. Electrochemistry Communications, v. 8, p. 1665-1670, 2006. [full text]

09. CRESPILHO, F. N.; ZUCOLOTTO, V.; OLIVEIRA, O. N.; NART, F. C. Electrochemistry of layer-by-layer films: a review. International Journal of Electrochemical Science, v. 1, p. 194-214, 2006. [full text]

08. SIQUEIRA, J. R.; GASPAROTTO, L. H. S.; CRESPILHO, F. N.; CARVALHO, A. J. F. ; ZUCOLOTTO, V.; OLIVEIRA, O. N. Physicochemical properties and sensing ability of metallophthalocyanines/chitosan nanocomposites. Journal of Physical Chemistry. B, v. 110, n.in press, p. 22690-22694, 2006. [full text]

2005

07. CRESPILHO, F. N.; ZUCOLOTTO, V.; SIQUEIRA, J. R.; CONSTANTINO, C. J. L.; NART, F. C.; OLIVEIRA, O. N. Immobilization of humic acid in nanostructured layer-by-layer films for sensing applications. Environmental Science & Technology, EUA, v. 39, p. 5385-5289, 2005. [full text]

2004

06. CRESPILHO, F. N.; SANTANA, C. G.; REZENDE, M. O. O. Tratamento de efluente da industria de processamento de coco utilizando eletroflotação. Química Nova, v. 27, n.3, p. 2-5, 2004. [full text]

05. CRESPILHO, F. N.; REZENDE, M. O. O. Eletrodos de carbono modificados com acidos húmicos: estudo e determinação de metais em meio aquoso. Química Nova, v. 27, p. 964-969, 2004. [full text]

2003

04. CRESPILHO, F. N.; SANTANA, C. G.; REZENDE, M. O. O. Eletrocoagulação aplicada no tratamento de águas residuárias. Saneamento Ambiental, v. 94, p. 32-36, 2003.

03. CRESPILHO, F. N.; SILVA, W. T. L.; REZENDE, M. O. O. Estudo, por via eletroquímica, da interação entre o herbicida metribuzin e os ácidos húmicos de vermicomposto. Anais da Associação Brasileira de Química, v. 52, n.2, p. 1-4, 2003. [full text]

02. CRESPILHO, F. N.; SANTANA, C. G.; REZENDE, M. O. O. Tratamento de efluentes industriais por eletroflotação: ciência e aplicação. Gerenciamento Ambiental, São Paulo, v. 5, p. 38-41, 2003.

2002

01. CRESPILHO, F. N.; MESSIAS, R. A.; REZENDE, M. O. O. Determinação de cobre em aguardente de cana por voltametria cíclica utilizando eletrodo de pasta de carbono modificado com ácidos húmicos. Anais da Associação Brasileira de Química, v. 51, p. 63-67, 2002.

CASTRO, K. R.; ALMEIDA, S. V.; FARIA, R. C.; CRESPILHO, F. N.; Fundamentals for Virus and Antigen Detection in Immunotechnologies. In: Advances in Bioelectrochemistry. Springer, v. 3, p.31-49, 2022.
MATTIOLI, I. A.; CRESPILHO, F. N.; Graphene-based bioelectronics. In: Advances in Bioelectrochemistry. Springer, v. 4, p.129-145, 2022.
BERTAGLIA, T.; FARIA, L. C. I.; CLARINDO, J. E. S.; CRESPILHO, F. N. Bioinspired Batteries: Using Nature-Inpired Materials in Greener and Safer Energy Storage Technologies. In: Advances in Bioelectrochemistry. Springer, v.4, p.63-87, 2022.
PACHECO, J. C.; SEDENHO, G. C.; CRESPILHO, F. N. Bioelectrosynthesis of Value-Added Compound Procuduction. In: Advances in Bioelectrochemistry, Springer, v. 4, p.29-47, 2022.
PFEREIRA, A. R.; MELO, A. F. A. A.; CRESPILHO, F. N.; OLIVEIRA JR, O. N. Combining Polymers, Nanomaterials, and Biomolecules: Nanostructured Films with Functional Properties and Applications. In Nanostructure and Science Technology. Springer, p. 481-508, 2021.
LUZ, R. A.; PEREIRA, A. R.; IOST, R. M and CRESPILHO, F. N. Biofuel Cells. In: Nanoenergy. Springer, Cham, 2018. p. 161-190.
SEDENHO, G. C., PEREIRA, A. R., PAGNONCELLI, K. C., DE SOUZA, J. C. P., & CRESPILHO, F. N.. Implantable Enzyme-Based Biofuel Cells. In: Reference Module in Chemistry, Molecular Sciences and Chemical Engineering: Encyclopedia of Interfacial Chemistry; Elsevier,2018. V.1, 248-260.
Olyveira, G. M.; IOST, R. M.; LUZ, R. A. S.; CRESPILHO, F. N. Biofuel Cells: Bioelectrochemistry Applied to Generation of Green Electricity. In: LEITE, E. R. and SOUZA (Org.). Nanoenergy: Nanotechnology Applied for Energy Production. Berlin: Springer-Verlag, 2012, v. III, p. 2-23.
LUZ, R. A. S.; IOST, R. M.; CRESPILHO, F. N. Nanomaterials for Biosensors and Implantable Biodevices. In: CRESPILHO, F. N. (Org.). Nanobioelectrochemistry: From Implantable Biosensors to Green Power Generation. 1^st ed. Berlin: Springer-Verlag, 2012, v. 1, p. 27-50.
NANTES, I. L.; CRESPILHO, F. N.; MUGNOL, K. C.; CHAVES, J. C. A.; LUZ, R. A. S.; NASCIMENTO, O. R.; PINTO, S. M. S. Magnetic Circular Dichroism Applied in the Study of Symmetry and Functional Properties of Porphyrinoids. In: RODGERS, D. S. (Org.). Circular Dichroism: Theory and Spectroscopy. New York: Nova Science Publishers, Inc., 2010, v.1, p. 1-23.
CRESPILHO, F. N. A Nanociência em Parceria com o Meio Ambiente (In Portuguese). In: Meio Ambiente Múltiplos Olhares. Campinas: Companhia da Escola, 2005, v. 1, p. 163-170.
CRESPILHO, F. N.; SILVA, W. C.; ZUCOLOTTO, V. Supramolecular Assemblies of Metallophtalocyanines: Physicochemical Properties and Applications. In: Catalysis and Phytochemistry in Heterogeneous Media. Kerala: Research Signpost, 2007.